Новые олигопиррольные макроциклические анионные рецепторы амидо-иминного типа с расширенной внутренней полостью
Schmuck, C., Carboxylate Binding by 2-(Guanidiniocarbonyl)pyrrole receptors in Aqueous Solvents: Improving the Binding Properties of Guanidinium Cations through Additional Hydrogen Bonds. Chem. Eur. J. 2000,6, (4), 709−718. S. Kamijo, C. Kanazawa, Y. Yamamoto. Copperot phosphine-catalyzed reaction of alkynes with isocyanides. Regioselective synthesis of substituted pyrroles controlled by the… Читать ещё >
Содержание
- 1. Введение
- 2. Обзор литературы
- 3. 1. Анионные рецепторы на основе а-карбоксамидопирролов
- 3. 1. 1. Некоторые особенности химии 1Н-пиррол-2 карбоновых кислот
- 3. 1. 2. Связывание анионов неполярными линейными амидопирролами
- 3. 1. 3. Полярные амидопиррольные анионные рецепторы
- 3. 2. Макроциклические азометины на основе производных пиррола
- 3. 2. 1. Олигопиррольные строительные блоки для построения макроциклических азометинов
- 3. 2. 2. Синтез и особенности координационной химии макроциклических иминов на основе производных пиррола
- 3. 3. Заключительные замечания
- 3. 1. Анионные рецепторы на основе а-карбоксамидопирролов
- 4. Обсуждение результатов
- 4. 1. Синтез макроциклических систем амидо-иминного типа, обоснование выбора строительных блоков
- 4. 2. Получение исходных кислот и альдегидов
- 4. 3. Диаминные строительные блоки-предшественники
- 4. 4. Макроциклические гетеродентатные лиганды на основе диформилбипиррола 105 и их комплексы с анионами
- 4. 5. Макроциклические гетеродентатные рецепторы на основе диформилдипирролилметана 103 и их комплексы
- 5. Выводы
- 6. Экспериментальная часть
- 6. 1. Синтезы исходных соединений
- 6. 2. Синтезы макроциклов
- 6. 3. Определение констант связывания анионов
- 6. 3. 1. Вывод уравнения для константы связывания при вытеснительном титровании
Новые олигопиррольные макроциклические анионные рецепторы амидо-иминного типа с расширенной внутренней полостью (реферат, курсовая, диплом, контрольная)
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