ΠΠ»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π½Π° ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉ
![ΠΠΈΡΡΠ΅ΡΡΠ°ΡΠΈΡ: ΠΠ»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π½Π° ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ
ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ
Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉ](https://niscu.ru/work/3541328/cover.png)
ΠΠ° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠΈΠ·ΠΈΠΊΠΎ-Ρ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΌΠ΅ΡΠΎΠ΄Π°ΠΌΠΈ Π‘ΠΠ, ΠΠΠ, Π Π€Π, ΠΌΠ°Π»ΠΎΡΠ³Π»ΠΎΠ²ΠΎΠΈ ΡΠ΅Π½ΡΠ³Π΅Π½ΠΎΠ²ΡΠΊΠΎΠΉ Π΄ΠΈΡΡΠ°ΠΊΡΠΈΠΈ, Π½ΠΈΠ·ΠΊΠΎΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΠΎΠΉ Π°Π΄ΡΠΎΡΠ±ΡΠΈΠΈ Π°Π·ΠΎΡΠ°, 111Π NH3 ΠΈ ΠΠΠ‘ Π°Π΄ΡΠΎΡΠ±ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ ΠΌΠΎΠ»Π΅ΠΊΡΠ»-Π·ΠΎΠ½Π΄ΠΎΠ² ΠΏΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΡ ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ Π²Π½Π°ΡΠ°Π»Π΅ ΠΊ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΠΌΠ΅Π·ΠΎΠΏΠΎΡ ΡΠ°Π·ΠΌΠ΅ΡΠΎΠΌ 20β30 Π Π² ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΠΊΡΠΈΡΡΠ°Π»Π»Π°Ρ , Π·Π°ΡΠ΅ΠΌ ΠΊ ΠΏΠΎΡΠ²Π»Π΅Π½ΠΈΡ Π½Π°Π½ΠΎΠΊΠΎΠΌΠ½ΠΎΠ·ΠΈΡΠΎΠ² ΡΠ΅ΠΎΠ»ΠΈΡ /ΠΠ‘Π-41 ΠΈ, Π½Π°ΠΊΠΎΠ½Π΅Ρ, ΠΊ ΠΏΠΎΠ»Π½ΠΎΠΌΡ ΠΏΡΠ΅Π²ΡΠ°ΡΠ΅Π½ΠΈΡ ΡΠ΅ΠΎΠ»ΠΈΡΠ°… Π§ΠΈΡΠ°ΡΡ Π΅ΡΡ >
- Π‘ΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅
- ΠΡΠ΄Π΅ΡΠΆΠΊΠ°
- ΠΠΈΡΠ΅ΡΠ°ΡΡΡΠ°
- ΠΡΡΠ³ΠΈΠ΅ ΡΠ°Π±ΠΎΡΡ
- ΠΠΎΠΌΠΎΡΡ Π² Π½Π°ΠΏΠΈΡΠ°Π½ΠΈΠΈ
Π‘ΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅
- ΠΠΠΠΠ ΠΠΠ’ΠΠ ΠΠ’Π£Π Π«
- ΠΠ»Π°Π²Π° 1. Π‘ΠΏΠΎΡΠΎΠ±Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΠ»ΡΡ
ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ²
- 1. 1. ΠΠ΅Π½ΠΎΠΌΠΈΠ½ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅
- 1. 2. Π‘ΠΈΠ½ΡΠ΅Π· Ρ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ ΡΡΠ΅ΡΠΎΠ΄Π½ΡΡ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»ΠΎΠ²
- 1. 3. Π‘ΠΈΠ½ΡΠ΅Π· Π² ΠΏΡΠΈΡΡΡΡΡΠ²ΠΈΠΈ Π΄Π²ΡΡ ΡΠ΅ΠΌΠΏΠ»Π°ΡΠΎΠ²
- 4. Π‘ΠΈΠ½ΡΠ΅Π· ΡΠ»ΠΎΠΈΡΡΡΡ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ²
- 5. ΠΡΠ΅Π²ΡΠ°ΡΠ΅Π½ΠΈΠ΅ Ρ1Π΅Π½ΠΎΠΊ ΠΌΠ΅ΡΠ½ΠΎΡΠΈΡΡΠΎΠ³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° Π² ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΠΉ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»
- 1. 6. ΠΠ°ΡΠ°ΡΠΈΠ²Π°Π½ΠΈΠ΅ ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠ³ΠΎ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»Π° Π½Π° ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΡΠ°Π·Ρ
- 1. 7. ΠΠ°Π½Π΅ΡΠ΅Π½ΠΈΠ΅ ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ Π·Π°ΡΠΎΠ΄ΡΡΠ΅ΠΉ Π½Π° ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΠΉ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»
- 1. 8. Π‘ΠΈΠ½ΡΠ΅Π· ΠΈΠ· Π·Π°ΡΠΎΠ΄ΡΡΠ΅ΠΉ ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΠΎΠΉ ΡΠ°Π·Ρ
- 1. 9. Π§Π°ΡΡΠΈΡΠ½Π°Ρ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΡ ΡΠ΅ΠΎΠ»ΠΈΡΠ°
- 5. ΠΡΠ΅Π²ΡΠ°ΡΠ΅Π½ΠΈΠ΅ Ρ1Π΅Π½ΠΎΠΊ ΠΌΠ΅ΡΠ½ΠΎΡΠΈΡΡΠΎΠ³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° Π² ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΠΉ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»
- 2. 1. ΠΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΡ
Π°Π»ΠΊΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»ΠΎΠ²
- 2. 1. 1. ΠΠΎΠΌΠΎΠ³Π΅Π½Π½ΡΠ΅ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΠΌΠΈΠ½Π΅ΡΠ°Π»ΡΠ½ΡΡ ΠΈ ΠΎΡ1Π°Π½ΠΈΡΠ΅ΡΠΊΠΈΡ ΠΊΠΈΡΠ»ΠΎΡ
- 2. 1.2 ΠΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠ»ΠΎΠΈΡΡΡΡ
ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»ΠΎΠ²
- 2. 1. 3. ΠΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ ΠΏΠ° ΠΎΡΠ½ΠΎΠ²Π΅ 1Π΅1Π΅ΡΠΎΠΏΠΎΠ»ΠΈΠΊΠΈΡΠ»ΠΎΡ
- 4. ΠΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΠΈΠΎΠ½Π½ΡΡ ΠΆΠΈΠ΄ΠΊΠΎΡΡΠ΅ΠΉ
- 2. 1. 5. ΠΠ°ΡΠ°Π»ΠΈ ΡΠΎΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΠΌΠΎΠ΄ΠΈΡΠΈΡΠΈΡΠΎΠ²Π°Π½Π½ΡΡ ΠΌΠ΅Π·ΠΎΠ½ΠΎΡΠΈΡΡΡΡ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»ΠΎΠ²
- 2. 1. 6. ΠΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ²
- 2. 1. 7. ΠΡΠΎΠΌΡΡΠ»Π΅Π½Π½ΡΠ΅ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΡ Π°Π»ΠΊΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»ΠΎΠ²
- 2. 2. ΠΠ»ΠΈΡΠ½ΠΈΠ΅ ΠΏΠ°ΡΠ°ΠΌΠ΅ΡΡΠΎΠ² ΠΏΡΠΎΡΠ΅ΡΡΠ° Π½Π° ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΠ΅ Π°Π»ΠΊΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»ΠΎΠ²
- ΠΠ»Π°Π²Π° 3. ΠΠ±ΡΠ΅ΠΊΡ ΠΈ ΠΌΠ΅ΡΠΎΠ΄Ρ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ
- 3. 2. 1. Π₯ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠΉ Π°Π½Π°Π»ΠΈΠ·
- 3. 2. 3. ΠΠΈΠ·ΠΊΠΎ1ΡΠΌΠ½Π΅ΡΠ°ΡΡΡΠ½Π°Ρ Π°Π΄ΡΠΎΡΠ±ΡΠΈΡ Π°Π·ΠΎΡΠ°
- 3. 2. 4. Π‘ΠΊΠ°Π½ΠΈΡΡΡΡΠ°Ρ ΡΠ»Π΅ΠΊΡΡΠΎΠ½Π½Π°Ρ ΠΌΠΈΠΊΡΠΎΡΠΊΠΎΠΏΠΈΡ
- 3. 2. 5. ΠΡΠΎΡΠ²Π΅ΡΠΈΠ²Π°ΡΡΠ°Ρ ΡΠ»Π΅ΠΊΡΡΠΎΠ½Π½Π°Ρ ΠΌΠΈΠΊΡΠΎΡΠΊΠΎΠΏΠΈΡ
- 6. ΠΠ-ΡΠ½Π΅ΠΊΠ³ΡΠΎΡΠΊΠΎΠΏΠΈΡ
- 8. Π’Π΅ΡΠΌΠΎ1ΡΠ°Π²ΠΈΠΌΠ΅Π³ΡΠΈΡ
- 3. 3 ΠΠ΅ΡΠΎΠ΄ΠΈΠΊΠΈ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΡΠ²ΠΎΠΉΡΡΠ²
- 3. 3. 1. ΠΠ΅ΡΠΎΠ΄ΠΈΠΊΠ° ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½ΠΈΡ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΡ ΡΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠ° ΠΏΡΠΈ Π°ΡΠΌΠΎΡΡΠ΅ΡΠ½ΠΎΠΌ Π΄Π°Π²Π»Π΅Π½ΠΈΠΈ
- 3. 3. 2. ΠΠ΅ΡΠΎΠ΄ΠΈΠΊΠ° ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½ΠΈΡ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΡ ΡΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠ° ΠΏΡΠΈ ΠΏΠΎΠ²ΡΡΠ΅Π½Π½ΠΎΠΌ Π΄Π°Π²Π»Π΅Π½ΠΈΠΈ
- 3. 3. 3. Π₯ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΠΉ Π°Π½Π°Π»ΠΈΠ· ΠΏΡΠΎΠ΄ΡΠΊΡΠΎΠ² ΡΠ΅Π°ΠΊΡΠΈΠΈ
- 3. 3. 4. ΠΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΠ°Π»ΡΠ½ΡΠΉ Π°Π½Π°Π»ΠΈΠ· ΠΏΡΠΎΠ΄ΡΠΊΡΠΎΠ² ΡΠ΅Π°ΠΊΡΠΈΠΈ
- ΠΠ»Π°Π²Π° 4. Π€ΠΈΠ·ΠΈΠΊΠΎ-Ρ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΠΈΠ·Π° ΡΠΈΠ½ΡΠ΅Π·ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅ΠΌΠ½ΠΎΡΠΈΠ΅ΡΡ ΠΎΠ±ΡΠ°Π·ΡΠΎΠ²
- 4. 5. 1. ΠΠΎΠ»ΠΈΡΠ΅ΡΡΠ²ΠΎ ΠΈ ΡΠΈΠ»Π° ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ ΡΠ΅Π½ΡΡΠΎΠ²
- 4. 5. 2. ΠΡΠΈΡΠΎΠ΄Π° ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ ΡΠ΅Π½ΡΡΠΎΠ²
- 3. ΠΠΎΡΡΡΠΏΠ½ΠΎΡΡΡ ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ
ΡΠ΅Π½ΡΡΠΎΠ²
- 4. 6. ΠΠ»ΠΈΡΠ½ΠΈΠ΅ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΠΈ Π½Π° ΡΠΈΠ·ΠΈΠΊΠΎ-Ρ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΎΠ±ΡΠ°Π·ΡΠΎΠ²
- 5. 1. ΠΠΎΡΠ»Π΅Π΄ΠΎΠ²Π°ΡΠ΅Π»ΡΠ½ΠΎΡΡΡ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΠΏΡΠΎΠ΄ΡΠΊΡΠΎΠ² ΡΠ΅Π°ΠΊΡΠΈΠΈ
- 5. 2. ΠΠ»ΠΈΡΠ½ΠΈΠ΅ ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΡ ΡΠ΅Π°ΠΊΡΠΈΠΈ
- 5. 3. ΠΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΌΠ΅Π·ΠΎΠΈΠΎΡΠΈΡΡΡΡ ΠΌΠΎΡΠ΄Π΅ΠΏΠΈΡΠΎΠ²
- 5. 4. ΠΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΡ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ² ΠΠΠ
- 6. 1. ΠΠΎΡΠ»Π΅Π΄ΠΎΠ²Π°ΡΠ΅Π»ΡΠ½ΠΎΡΡΡ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΠΏΡΠΎΠ΄ΡΠΊΡΠΎΠ² ΡΠ΅Π°ΠΊΡΠΈΠΈ
- 6. 2 ΠΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΡ ΠΌΠΎΡΠ΄Π΅Π½ΠΈΡΠΎΠ²
- 3. ΠΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΌΠ΅Π·ΠΎΠΈΠΎΡΠΈΡΡΡΡ
ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ² ΠΠΠ
- 6. 4. ΠΡΠ±ΠΎΡ ΠΎΠΏΡΠΈΠΌΠ°Π»ΡΠ½ΡΡ
ΡΡΠ»ΠΎΠ²ΠΈΠΉ ΡΠ΅Π°ΠΊΡΠΈΠΈ
- 6. 4. 1. ΠΠ»ΠΈΡΠ½ΠΈΠ΅ ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΡ
- 6. 4. ΠΡΠ±ΠΎΡ ΠΎΠΏΡΠΈΠΌΠ°Π»ΡΠ½ΡΡ
ΡΡΠ»ΠΎΠ²ΠΈΠΉ ΡΠ΅Π°ΠΊΡΠΈΠΈ
- 6. 4. 3. ΠΠ»ΠΈΡΠ½ΠΈΠ΅ ΠΌΠ°ΡΡΠΎΠ²ΠΎΠΉ ΡΠΊΠΎΡΠΎΡΡΠΈ ΠΏΠΎΠ΄Π°ΡΠΈ
- 5. Π‘ΡΠ°Π²Π½Π΅Π½ΠΈΠ΅ ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΡ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠΎΠ² Ρ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»ΡΠΌΠΈ ΠΏΡΠΎΠΌΡΡΠ»Π΅Π½Π½ΡΡ ΠΏΡΠΎΡΠ΅ΡΡΠΎΠ²
ΠΠ»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π½Π° ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉ (ΡΠ΅ΡΠ΅ΡΠ°Ρ, ΠΊΡΡΡΠΎΠ²Π°Ρ, Π΄ΠΈΠΏΠ»ΠΎΠΌ, ΠΊΠΎΠ½ΡΡΠΎΠ»ΡΠ½Π°Ρ)
Π Π½Π°ΡΡΠΎΡΡΠ΅Π΅ Π²ΡΠ΅ΠΌΡ Π²ΠΎΠ·ΡΠ°ΡΡΠ°ΡΡΠΈΠΉ ΡΠΏΡΠΎΡ Π½Π° ΠΌΠΎΡΡΠΈΠ΅ ΡΡΠ΅Π΄ΡΡΠ²Π°, ΠΎΠ±Π»Π°Π΄Π°ΡΡΠΈΠ΅ ΡΡΡΠΉΡΠΈΠ²ΡΠΌ ΠΏΠ΅Π½ΠΎΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ ΠΈ Π±ΠΈΠΎΡΠ°Π·ΡΡΡΠ°Π΅ΠΌΠΎΡΡΡΡ, ΠΎΠ±ΡΡΠ»Π°Π²Π»ΠΈΠ²Π°Π΅Ρ Π½Π΅ΠΎΠ±Ρ ΠΎΠ΄ΠΈΠΌΠΎΡΡΡ ΡΠ°Π·ΡΠ°Π±ΠΎΡΠΊΠΈ Π½ΠΎΠ²ΡΡ ΡΠΏΠΎΡΠΎΠ±ΠΎΠ² ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΠ³ΠΎ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ Π»ΠΈΠ½Π΅ΠΈΠ½ΡΡ Π°Π»ΠΊΠΈΠ»Π±Π΅Π½ΡΠ»ΠΎΠ² Ρ ΠΏΡΠ΅ΠΎΠ±Π»Π°Π΄Π°Π½ΠΈΠ΅ΠΌ 2-ΡΠ΅Π½ΠΈΠ»Π°Π»ΠΊΠ°Π½ΠΎΠ², ΠΊΠΎΡΠΎΡΡΠ΅ ΠΏΡΡΠ΅ΠΌ ΡΡΠ»ΡΡΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΌΠΎΠ³ΡΡ Π±ΡΡΡ ΠΏΠ΅ΡΠ΅Π²Π΅Π΄Π΅Π½Ρ ΠΈ ΠΏΠΎΠ²Π΅ΡΡ Π½ΠΎΡΡΠ½ΠΎ-Π°ΠΊΡΠ²ΠΏΡΠ΅ Π²Π΅ΡΠ΅ΡΡΠ²Π° ΠΠΊΠΎΠ»ΠΎ 90% ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΡ ΠΏΡΠΎΠΌΡΡΠ»Π΅Π½Π½ΡΡ ΠΌΠΎΡΠ½ΠΎΡΡΠ΅ΠΉ, Π½ΠΎ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΡΡΠ²Ρ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΡ Π°Π»ΠΊΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»ΠΎΠ² ΠΎΡΠ½ΠΎΠ²Π°Π½ΠΎ Π½Π° Π°Π»ΠΊΡΡΡΠΎΠ²Π°Π½ΠΈΠΈ Π±Π΅Π½Π·ΠΎΠ»Π° ΠΎΠ»Π΅ΡΠΈΠΈΠ°ΠΌΠΈ Π² ΠΏΡΠΈΡΡΡΡΡΠ²ΠΈΠΈ ΡΠΌΠΎΠ³Π΅ΠΏΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ AICI3 ΠΈΠ»ΠΈ HF, ΠΊΠΎΡΠΎΡΡΠ΅ ΠΏΡΠΈΠ²ΠΎΠ΄ΡΡ ΠΊ ΠΊΠΎΡΡΠΎΠ·ΠΈΠΈ Π°ΠΏΠΏΠ°ΡΠ°ΡΡΡΡ, Π±ΠΎΠ»ΡΡΠΎΠΌΡ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Ρ ΠΎΡΡ ΠΎΠ΄ΠΎΠ², Π·Π°Π³ΡΡΠ·Π½Π΅Π½ΠΈΡ ΠΎΠΊΡΡΠΆΠ°ΡΡΠ΅ΠΉ ΡΡΠ΅Π΄Ρ ΠΈ Π½Π΅ ΡΠ΅Π³Π΅Π½Π΅ΡΠΈΡΡΡΡΡΡ. Π ΡΠ²ΡΠ·ΠΈ Ρ ΡΡΠΈΠΌ ΠΏΠΎΠΈΡΠΊ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΡΡ Π³Π΅ΡΠ΅ΡΠΎΠ³Π΅Π½Π½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΡΠΊΠ°Π·Π°Π½Π½ΠΎΡ ΠΏΡΠΎΡΠ΅ΡΡΠ°, Π»ΠΈΡΠ΅Π½Π½ΡΡ ΠΏΠ΅ΡΠ΅ΡΠΈΡΠ»Π΅Π½Π½ΡΡ Π½Π΅Π΄ΠΎΡΡΠ°ΡΠΊΠΎΠ², ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»ΡΠ΅Π³ Π½Π΅ ΡΡΡΠΊΠΎ Π±ΠΎΠ»ΡΡΠΎΠΉ Π½Π°ΡΡΠ½ΡΠΉ, Π½ΠΎ ΠΈ ΠΏΡΠ°ΠΊΡΠΈΡΠ΅ΡΠΊΠΈΠΉ ΠΈΠ½ΡΠ΅ΡΠ΅Ρ.
Π ΠΏΠ΅ΡΡΠΏΠ΅ΠΊΡΠΈΠ²Π½ΡΠΌ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°ΠΌ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° ΠΎΠ»Π΅ΡΠΈΠΈΠ°ΠΌΠΈ ΠΎΡΠ½ΠΎΡΡΡΡΡ ΡΠ΅ΠΎΠ»ΠΈΡΡ, ΠΎΠ±Π»Π°Π΄Π°ΡΡΠΈΠ΅ Π²ΡΡΠΎΠΊΠΎΠΉ ΠΊΠΈΡΠ»ΠΎΡΠ½ΠΎΡΡΡΡ, Ρ ΠΎΡΠΎΡΠ΅ΠΉ ΡΠ΅ΡΠΌΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΈ Π³ΠΈΠ΄ΡΠΎΡΠ΅ΡΠΌΠ°Π»ΡΠ½ΠΎΠΉ ΡΡΠ°Π±ΠΈΠ»ΡΠ½ΠΎΡΡΠΎ. ΠΡΠΎΠΌΠ΅ ΡΠΎΠ³ΠΎ, ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² 01ΠΊΡΡΠ½Π°Π΅Π³ ΠΏΡΠΈΠ½ΡΠΈΠΏΠΈΠ°Π»ΡΠ½ΠΎ Π½ΠΎΠ²ΡΠ΅ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΠ³ΠΎ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΡΠ΅Π»Π΅Π²ΡΡ ΠΏΡΠΎΠ΄ΡΠΊΡΠΎΠ² Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π»Π°Π³ΠΎΠ΄Π°ΡΡ ΡΠΏΠ΅ΡΠΈΡΠΈΠΊΠ΅ ΠΏΡΠΎΡΡΡΠ°Π½ΡΡΠ²Π΅Π½Π½ΠΎΠΉ ΠΊΠΎΠ½ΡΠΈΠ³ΡΡΠ°ΡΠΈΠΈ ΠΈΡ ΡΠ²ΠΎΠ±ΠΎΠ΄Π½ΠΎΡ Π²Π½ΡΡΡΠΈΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΡΠ΅ΡΠΊΠΎΡ ΠΏΡΠΎΡΡΡΠ°Π½ΡΡΠ²Π°, ΡΠΎΠ·Π΄Π°ΡΡΠ΅Ρ ΡΠ½ΠΈΠΊΠ°Π»ΡΠ½ΡΠΉ ΡΡΡΠ΅ΠΊΡ ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΠΎΠΉ ΡΡΠ΅ΡΠ΅ΠΎΡΠ΅Π»Π΅ΠΊΠ³ΠΈΠ²Π½ΠΎΡΡΠΈ ΠΏΠΎ Π»ΠΈΠ½Π΅ΠΈΠ½ΡΠΌ Π°Π»ΠΊΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»Π°ΠΌ. ΠΠ΄Π½Π°ΠΊΠΎ ΡΡΡΠ΅ΡΡΠ²Π΅Π½Π½ΡΠΌ Π½Π΅Π΄ΠΎΡΡΠ°ΡΠΊΠΎΠΌ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ² ΡΠ²Π»ΡΡΡΡΡ Π΄ΠΈΡΡΡΠ·ΠΈΠΎΠ½Π½ΡΠ΅ (ΠΌΡΠ°ΠΏΠΈΡΠ΅ΠΈΠΈΡ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ° ΠΊΡΡΠΏΠ½ΡΡ ΠΌΠΎΠ»Π΅ΠΊΡΠ» Π² ΠΈΡ ΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΠ΅, ΠΏΡΠΈΠ²ΠΎΠ΄ΡΡΠΈΠ΅ ΠΊ ΡΠ½ΠΈΠΆΠ΅Π½ΠΈΡ ΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°, Π° Π³Π°ΠΊΠΆΠ΅ ΠΊ Π±Π»ΠΎΠΊΠΈΡΠΎΠ²ΠΊΠ΅ ΠΏΠΎΡ ΠΏΡΠΎΠ΄ΡΠΊΡΠ°ΠΌΠΈ ΠΈ, ΠΊΠ°ΠΊ ΡΠ»Π΅Π΄ΡΡΠ²ΠΈΠ΅, ΠΊ Π±ΡΡΡΡΠΎΠΉ Π΄Π΅Π·Π°ΠΊΡΠΈΠ²Π°ΡΠΈΠΈ.
ΠΠ·Π²Π΅ΡΡΠ½ΠΎ, ΡΡΠΎ ΡΡΠΈ ΠΎΠ³ΡΠ°Π½ΠΈΡΠ΅Π½ΠΈΡ ΠΌΠΎΠΆΠ½ΠΎ ΡΠ²Π΅ΡΡΠΈ ΠΊ ΠΌΠΈΠ½ΠΈΠΌΡΠΌΡ ΠΈΠ»ΠΈ Π΄Π°ΠΆΠ΅ ΠΈΠΎΠ»ΠΈΠΎΡΡΡΠΎ ΡΠΏΡΡΡ ΠΏΡΡΠ΅ΠΌ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ½ΡΡ ΠΏΠΎΡ Π² ΡΠ΅ΠΎΠ»ΠΈΠ³ΠΏΠΎΠΌ ΠΊΡΠΈΡΡΠ°Π»Π»Π΅. Π ΡΡΠΎΠΌ ΠΎΡΠ½ΠΎΡΠ΅Π½ΠΈΠΈ Π½Π°ΠΈΠ±ΠΎΠ»Π΅Π΅ ΠΏΠ΅ΡΡΠΏΠ΅ΠΊΡΠΈΠ²Π½ΡΠΌ ΠΏΡΠ΅Π΄ΡΠ³Π°Π²Π»ΡΠ΅1ΡΡ ΡΠΎΠ·Π΄Π°Π½ΠΈΠ΅ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»ΠΎΠ² Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉ, ΡΠΎΡΠ΅ΡΠ°ΡΡΠΈΡ Π²ΡΡΠΎΠΊΡΡ ΠΊΠΈΡΠ»ΠΎΡΠ½ΠΎΡΡΡ ΠΈ ΡΠ½ΠΈΠΊΠ°Π»ΡΠ½ΡΡ ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΡΡ ΡΡΠ΅ΡΠ΅ΠΎΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ ΡΠ΅ΠΎΠ»ΠΈΡΠ² Ρ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ½ΡΠΌΠΈ Ρ Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠ°ΠΌΠΈ ΠΌΡΠ·ΠΎΠΏΠΎΡΠΈΡΡΡΡ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»ΠΎΠ² ΠΠ³ΠΎ ΠΎΠ±ΡΡΠ»Π°Π²Π»ΠΈΠ²Π°Π΅Ρ Π°ΠΊΡΡΠ°Π»ΡΠ½ΠΎΡΡΡ Π΄Π°Π½Π½ΠΎΠΉ ΡΠ°Π±ΠΎΡΡ, Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½Π½ΠΎΠΉ Π½Π° ΡΠ°Π·ΡΠ°Π±ΠΎΡΠΊΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΠΎΠΉ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠ΅ΠΎΠ»ΠΈΡΠ° Beta (ΠΠΠ) ΠΈ ΠΌΠΎΡΠ΄Π΅Π½ΠΈΡΠ° (MOR) Π΄Π»Ρ ΠΏΡΠΎΡΠ΅ΡΡΠ° Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1.
Π¦Π΅Π»Ρ ΡΠ°Π±ΠΎΡΡ Π·Π°ΠΊΠ»ΡΡΠ°Π»Π°ΡΡ Π² ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΈΠΈ ΠΎΡΠ½ΠΎΠ²Π½ΡΡ Π·Π°ΠΊΠΎΠ½ΠΎΠΌΠ΅ΡΠ½ΠΎΡΡΠ΅ΠΉ ΡΠ΅Π°ΠΊΡΠΈΠΈ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π½Π° Π½ΠΎΠ²ΡΡ ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅ΡΠ½ΠΎΡΠΈΡΡΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉ, Π° ΡΠ°ΠΊΠΆΠ΅ Π² ΡΠ°Π·ΡΠ°Π±ΠΎΡΠΊΠ΅ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΡΠΈΡ ΡΠΈΡΡΠ΅ΠΌ Π²ΡΡΠΎΠΊΠΎΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΠ³ΠΎ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°, ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡΡΠ΅Ρ ΠΈΠ·Π±ΠΈΡΠ°Π³Π΅Π»ΡΠΏΠΎ ΠΏΠΎΠ»ΡΡΠ°ΡΡ Π»ΠΈΠ½Π΅ΠΈΠ½ΡΠ΅ ΡΠ΅Π½ΠΈΠ»Π΄ΠΎΠ΄Π΅ΠΊΠ°Π½Ρ Ρ ΠΏΡΠ΅ΠΎΠ±Π»Π°Π΄Π°Π½ΠΈΠ΅ΠΌ 2-ΡΠ΅Π½ΠΈΠ»Π΄ΠΎΠ΄Π΅ΠΊΠ°Π½Π°.
ΠΠΠΠΠ ΠΠΠ’ΠΠ ΠΠ’Π£Π Π«
Π²ΡΠ²ΠΎΠ΄Ρ
1 ΠΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½ Π½ΠΎΠ²ΡΠΉ ΡΠΏΠΎΡΠΎΠ± ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΡ ΡΠ΅Π½ΠΈΠ»Π΄ΠΎΠ΄Π΅ΠΊΠ°Π½ΠΎΠ², ΠΎΡΠ½ΠΎΠ²Π°Π½Π½ΡΠΉ Π½Π° Π³Π°Π·ΠΎ-ΠΆΠΈΠ΄ΠΊΠΎΡΠ°Π·Π½ΠΎΠΌ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠΌ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΠΈ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π² ΠΏΡΠΎΡΠΎΡΠ½ΡΡ ΡΡΠ»ΠΎΠ²ΠΈΡΡ Π² ΠΏΡΠΈΡΡΡΡΡΠ²ΠΈΠΈ ΡΠ΅ΠΎΠ»ΠΈΡΠΈΠΎΠ³ΠΎ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ° Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉ.
2. ΠΠ΅ΡΠΎΠ΄ΠΎΠΌ Π³ΠΈΠ΄ΡΠΎΡΠ΅ΡΠΌΠ°Π»ΡΠ½ΠΎΠΉ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΠΈ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ² MOR ΠΈ ΠΠΠ Π² ΡΠ°ΡΠ³Π²ΠΎΡΠ΅ ΡΠ΅Π»ΠΎΡΠΈ ΠΈ Π±ΡΠΎΠΌΠΈΠ΄Π° ΡΠ΅ΡΠΈΠ»ΡΡΠΈΠΌΠ΅ΡΠΈΠ»Π°ΠΌΠΌΠΎΠ½ΠΈΡ ΠΏΠΎΠ»ΡΡΠ΅Π½Ρ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Ρ ΠΊΠΎΠΌΠ±ΠΈΠ½ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠΎΠΉΠΏΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ Π²Π°ΡΡΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΠΈ ΡΠ΅Π»ΠΎΡΠΈ ΠΏΠΎΠ·Π²ΠΎΠ»ΡΠ΅Ρ Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½Π½ΠΎ ΠΈΠ·ΠΌΠ΅Π½ΡΡΡ ΡΡΠ΅ΠΏΠ΅Π½Ρ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΠΈ ΠΈ ΠΏΠΎΠ»ΡΡΠ°ΡΡ ΠΊΠ°1Π°Π»ΠΈΠ·Π°ΡΡΡ Ρ ΡΠ°Π·Π»ΠΈΡΠ½ΡΠΌ Π²ΠΊΠ»Π°Π΄ΠΎΠΌ ΠΌΠΈΠΊΡΠΎΠΈ ΠΌΠ΅Π·ΠΎΠΏΠΎΡ.
3. ΠΠ° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠΈΠ·ΠΈΠΊΠΎ-Ρ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΌΠ΅ΡΠΎΠ΄Π°ΠΌΠΈ Π‘ΠΠ, ΠΠΠ, Π Π€Π, ΠΌΠ°Π»ΠΎΡΠ³Π»ΠΎΠ²ΠΎΠΈ ΡΠ΅Π½ΡΠ³Π΅Π½ΠΎΠ²ΡΠΊΠΎΠΉ Π΄ΠΈΡΡΠ°ΠΊΡΠΈΠΈ, Π½ΠΈΠ·ΠΊΠΎΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΠΎΠΉ Π°Π΄ΡΠΎΡΠ±ΡΠΈΠΈ Π°Π·ΠΎΡΠ°, 111Π NH3 ΠΈ ΠΠΠ‘ Π°Π΄ΡΠΎΡΠ±ΠΈΡΠΎΠ²Π°Π½Π½ΡΡ ΠΌΠΎΠ»Π΅ΠΊΡΠ»-Π·ΠΎΠ½Π΄ΠΎΠ² ΠΏΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΡ ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ Π²Π½Π°ΡΠ°Π»Π΅ ΠΊ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΠΌΠ΅Π·ΠΎΠΏΠΎΡ ΡΠ°Π·ΠΌΠ΅ΡΠΎΠΌ 20−30 Π Π² ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ ΠΊΡΠΈΡΡΠ°Π»Π»Π°Ρ , Π·Π°ΡΠ΅ΠΌ ΠΊ ΠΏΠΎΡΠ²Π»Π΅Π½ΠΈΡ Π½Π°Π½ΠΎΠΊΠΎΠΌΠ½ΠΎΠ·ΠΈΡΠΎΠ² ΡΠ΅ΠΎΠ»ΠΈΡ /ΠΠ‘Π-41 ΠΈ, Π½Π°ΠΊΠΎΠ½Π΅Ρ, ΠΊ ΠΏΠΎΠ»Π½ΠΎΠΌΡ ΠΏΡΠ΅Π²ΡΠ°ΡΠ΅Π½ΠΈΡ ΡΠ΅ΠΎΠ»ΠΈΡΠ° Π² ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΠΉ ΠΠ‘Π-41- ΠΏΡΠΈ ΡΡΠΎΠΌ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΡ ΡΠΈΠ»ΡΠ½ΡΡ Π±ΡΠ΅ΠΈΡΡΠ΅Π΄ΠΎΠ²ΡΠΊΠΈΡ ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ ΡΠ΅Π½ΡΡΠΎΠ², Π΄ΠΎΡΡΡΠΏΠ½ΡΡ Π΄Π»Ρ ΠΏΠΈΡΠΈΠ΄ΠΈΠ½ΠΎΠ²ΡΡ ΠΎΡΠ½ΠΎΠ²Π°Π½ΠΈΠΈ, ΡΠ½Π°ΡΠ°Π»Π° ΡΠ²Π΅Π»ΠΈΡΠΈΠ²Π°Π΅ΡΡΡ, Π° Π·Π°ΡΠ΅ΠΌ ΠΏΠ°Π΄Π°Π΅Ρ.
4. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½Ρ ΠΎΡΠ½ΠΎΠ²Π½ΡΠ΅ Π·Π°ΠΊΠΎΠ½ΠΎΠΌΠ΅ΡΠ½ΠΎΡΡΠΈ ΡΠ΅Π°ΠΊΡΠΈΠΈ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π½Π° ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΡ MOR ΠΈ ΠΠΠ: ΡΠΎΠ·Π΄Π°Π½ΠΈΠ΅ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ½ΡΡ ΠΏΠΎΡ ΠΈ ΡΠ²Π΅Π»ΠΈΡΠ΅Π½ΠΈΠ΅ Π΄ΠΎΡΡΡΠΏΠ½ΠΎΡΡΠΈ ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ ΡΠ΅Π½ΡΡΠΎΠ² Π² ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠ΅ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΠΈ Π² ΠΌΡ1ΠΊΠΈΡ ΡΡΠ»ΠΎΠ²ΠΈΡΡ ΡΠΏΠΎΡΠΎΠ±ΡΡΠ²ΡΠ΅Ρ ΡΠ²Π΅Π»ΠΈΡΠ΅Π½ΠΈΡ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΏΡΠΈ ΡΠΎΡ ΡΠ°Π½Π΅Π½ΠΈΠΈ Π²ΡΡΠΎΠΊΠΎΠΉ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΏΠΎ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΠΌ ΡΠ΅Π½ΠΈΠ»Π΄ΠΎΠ΄Π΅ΠΊΠ°Π½Π°ΠΌΠ±ΠΎΠ»Π΅Π΅ 1Π»ΡΠ±ΠΎΠΊΠ°Ρ ΡΡΠ΅ΠΏΠ΅Π½Ρ ΡΠ΅ΠΊΡΠΈΡΡΠ°Π»Π»ΠΈΠ·Π°ΡΠΈΠΈ Π² ΠΠ‘Π-41 ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ ΠΊ ΡΠ½ΠΈΠΆΠ΅Π½ΠΈΡ ΠΊΠΎΠ½Π²Π΅ΡΡΠΈΠΈ ΠΈ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ, ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΠΌΠΎΡΠ΄Π΅Π½ΠΈΠ³Π° Π±ΠΎΠ»Π΅Π΅ Π°ΠΊΡΠΈΠ²Π½Ρ ΠΏΠΎ ΡΡΠ°Π²Π½Π΅Π½ΠΈΡ Ρ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠΌ ΠΠΠ
5. ΠΠ°ΠΉΠ΄Π΅Π½Ρ ΠΎΠΏΡΠΈΠΌΠ°Π»ΡΠ½ΡΠ΅ ΡΡΠ»ΠΎΠ²ΠΈΡ ΠΏΡΠΎΡΠ΅ΡΡΠ° Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅ΠΏΠΎΠΌ-1 Π½Π° ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ , ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°ΡΡΠΈΠ΅ ΠΌΠ°ΠΊΡΠΈΠΌΠ°Π»ΡΠ½ΡΠΉ Π²ΡΡ ΠΎΠ΄ ΡΠ΅Π»Π΅Π²ΠΎΡ ΠΏΡΠΎΠ΄ΡΠΊΡΠ° ΠΈ ΡΡΠ°Π±ΠΈΠ»ΡΠ½ΡΡ ΡΠ°Π±ΠΎΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ° Π²ΠΎ Π²ΡΠ΅ΠΌΠ΅Π½ΠΈ: ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ° 100 Β°C, Π΄Π°Π²Π»Π΅Π½ΠΈΠ΅ 3 ΠΠΠ°, ΠΌΠ°ΡΡΠΎΠ²Π°Ρ ΡΠΊΠΎΡΠΎΡΡΡ ΠΏΠΎΠ΄Π°ΡΠΈ ΡΠΌΠ΅ΡΠΈ 5−20 Ρ" 1, ΠΌΠΎΠ»ΡΠ½ΠΎΠ΅ ΡΠΎΠΎΡΠ½ΠΎΡΠ΅Π½ΠΈΠ΅ Π±Π΅Π½Π·ΠΎΠ»: Π΄ΠΎΠ΄Π΅ΡΡΠ½-1 =8:1.
6. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½Π° ΠΊΠΎΡΡΠ΅Π»ΡΡΠΈΡ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΈ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΠΈ Π±ΡΠ΅ΠΈΡΡΠ΅Π΄ΠΎΠ²ΡΠΊΠΈΡ ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ ΡΠ΅Π½ΡΡΠΎΠ², Π΄ΠΎΡΡΡΠΏΠ½ΡΡ Π΄Π»Ρ ΠΏΠΈΡΠΈΠ΄ΠΈΠ½Π°. ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΠΏΠΈΡΠΈΠ΄ΠΈΠ½ ΠΌΠΎΠΆΠ΅Ρ Π±ΡΡΡ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ ΠΌΠΎΠ»Π΅ΠΊΡΠ»Ρ-Π·ΠΎΠ½Π΄Π° Π΄Π»Ρ ΠΏΡΠΎΠ³Π½ΠΎΠ·ΠΈΡΠΎΠ²Π°Π½ΠΈΡ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠΉ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΡΡ ΡΠ΅ΠΎΠ»ΠΈΡΠΎΠ² Π² ΡΠ΅Π°ΠΊΡΠΈΠΈ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½ ΡΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1.
7. Π Π°Π·ΡΠ°Π±ΠΎΡΠ°Π½ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° Π΄ΠΎΠ΄Π΅ΡΠ΅Π½ΠΎΠΌ-1 Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΠΌΠΈΠΊΡΠΎ-ΠΌΠ΅Π·ΠΎΠΏΠΎΡΠΈΡΡΠΎΠ³ΠΎ ΠΌΠΎΡΠ΄Π΅Π½ΠΈΡΠ°, ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΠ²Π°ΡΡΠΈΠΉ ΠΊΠΎΠ½Π²Π΅ΡΡΠΈΡ Π΄ΠΎΠ΄ΡΡΠ΅Π½Π°-1 100% ΠΈ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ ΠΏΠΎ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΠΌ ΠΈΠ·ΠΎΠΌΠ΅ΡΠ°ΠΌ ΠΈ ΠΏΠΎ 2-ΡΠ΅Π½ΠΈΠ»Π΄ΠΎΠ΄Π΅ΠΊΠ°Π½Ρ Π²ΠΎ ΡΡΠ°ΠΊΡΠΈΠΈ ΡΠ΅Π½ΠΈΠ»Π΄ΠΎΠ΄Π΅ΠΊΠ°Π½ΠΎΠ² 92% ΠΈ 72%" ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²Π΅Π½Π½ΠΎ.
Π‘ΠΏΠΈΡΠΎΠΊ Π»ΠΈΡΠ΅ΡΠ°ΡΡΡΡ
- , G. Denes, N. Π Π‘. Vo, J.A. Lavigne, and S.T. Le. Production of porous materials by dealumination of alumina-rich zeolites, in Materials Research Society Symposium — Proceedings. 1995 Boston, MA, USA: Materials Research Society.
- Moreno, S. and G Poncelet, Dealumination of small- and large-port mordenites A comparative study. Microporous materials, 1997. 12(4−6 Amsterdam, Netherlands): p 197−222.
- Dong, S.-T., X.-W Li, D.-D. Li, Y.-H. Shi, H. Nie, and X.-II. Kang, Study on the formation of mesopore during hydrothermal dealumination of Y zeolite. Acta Physico -Chimica Sinica, 2002 18(3): p. 201−206.
- Groen, J.C., J.A. Moulijn, and J. Perez-Ramirez, Decoupling mesoporosity formation and acidity modification in ZSM-5 zeolites by sequential desilication-dealumination. Microporous and Mesoporous Materials, 2005. 87(2). p. 153−161.
- Kerr, G. Π., Chemistry of crystalline alumosilicates. V. Preparation of luminium-deficient faujasites. J. Phys. Chem, Part V, 1968 72 (7): p. 2594.
- Schmidt, I., C. Madsen, and C.J.H. Jacobsen, Confined space synthesis. A novel route to nanosized zeolites. Inorganic Chemistry, 2000. 39(11): p. 2279−2283.
- Kim, S.-S, J. Shah, and I'.J. Pinnavaia, Colloid-imprinted carbons as templates for the nanocasting synthesis of mesoporous ZSM-5 zeolite. Chemistry of Materials, 2003. 15(8): p. 1664−1668.
- Zhu, G., S. Qiu, F. Gao, D. Li, Y. 1Π», R. Wang, B. Gao, B. Li, Y. Guo, R. Xu, Z. Liu, and O. Tcrasaki, Template-assisted self-assembly of macro-micro bifunctional porous materials. Journal ofMaterials Chemistry, 2001. 11(6): p. 1687−1693.
- Jacobsen, C.J.II., Π‘. Madscn, J. Houzvicka, I. Schmidt, and A. Carlsson, Mesoporous zeolite single crystals 2. Journal of the American Chemical Society, 2000. 122(29): p. 7116−7117.
- Kustova, M.Y., P. Hasselriis, and C.H. Christensen, Mesoporous MEL type zeolite single crystal catalysts. Catalysis Letters, 2004. 96(3−4): p. 205−211.
- Schmidt, I, A. Boisen, E. Gustavsson, K. Stahl, S. Pehrson, S. Dahl, A. Carlsson, and C.J.I 1. Jacobsen, Carbon nanotube templated growth of mesoporous zeolite single crystals. Chemistry of Materials, 2001. 13(12) p 4416−4418.
- Garcia-Martinez, J., D. Cazorla-Amoros, A. Linares-Solano, and Y.S. Lin, Synthesis and characterisation of MFI-type zeolites supported on carbon materials. Microporous and Mesoporous Materials, 2001 42(2−3)-p 255−268.
- Janssen, A.H., I. Schmidt, C.J.II Jacobsen, A J. Koster, and K.P. de Jong, Exploratory study of mesopore templating with carbon during zeolite synthesis. Microporous and Mesoporous Materials, 2003. 65(1): p. 59−75.
- Iao, Y., H Kanoh, L. Abrams, and K. Kaneko, Mesopore-modified zeolites: Preparation, characterization, and applications Chemical Reviews, 2006. 106(3): p. 896−910.
- Beck, J.S., J.C. Vartuli, G.J. Kennedy, C.T. Kresge, R. W.J., and S. S.E., Chem. Mater., 1994. 6: p. 1816−1821.
- Karlsson, A., M. Stocker, and R. Schmidt, Composites of micro- and mesoporous materials: Simultaneous syntheses of ME1/MCM-41 like phases by a mixed template approach. Microporous and Mesoporous Materials, 1999. 27(2−3): p. 181−192.
- Karlsson, A. and M. Stocker. Enhanced hydrothermal stability obtained for in situ synthesized micro- and mesoporous MFI/MCM-41 like phases, in Studies in Surface Science and Catalysis 1999. Eger.
- Karlsson, Π., M. Stockcr, and Π. Schafer, In situ synthesis of micro- and mesoporous Al-MFI/MCM-41 like phases with high hydrothermal stability. Studies in Surface Science and Catalysis, 2000. 129: p. 99−106.
- Kim, D.S., S.-E. Park, and S.O. Kang, Microwave synthesis of micro-mesoporous composite material. Studies in Surfacc Scicnce and Catalysis, 2000. 129: p. 107−116.
- Prokesova, P., S. Mintova, J. Cejka, and T. Bein, Preparation of nanosized micro/mesoporous compositcs. Materials Science and Engineering C, 2003. 23(6−8): p. 1001−1005.
- Prokesova, P., S. Mintova, J. Cejka, and T. Bein, Preparation of nanosized micro/mesoporous composites via simultaneous synthesis of Beta/MCM-48 phases Microporous and Mesoporous Materials, 2003. 64(1−3): p. 165−174.
- Corma, A., V. Fornes, and F. Rey, Delaminated zeolites: An efficient support for enzymes. Advanced Materials, 2002. 14(1): p. 71−74.
- Corma, A and V. Fornes, Delaminated zeolites as active catalysts for processing large molecules. Studies in Surface Science and Catalysis, 2001. 135: p. 73−82.
- Corma, A, V. Fornes, J.M. Guil, S. Pcrgher, T.L.M. Maesen, and J.CJ. Buglass, Preparation, characterisation and catalytic activity of ITQ-2, a delaminated zeolite. Microporous and Mesoporous Materials, 2000. 38(2−3 Amsterdam, Netherlands), p. 301 309.
- Corma, A, V. Fornes, S.B. Pergher, T.L.M. Maesen, and J.G. Buglass, Delaminated zeolite precursors as selective acidic catalysts. Nature, 1998. 396(6709): p. 353−356.
- Corma, A, U. Diaz, M.E. Domine, and V. Fornes, A1FIQ-6 and I1IIQ-6: Synthesis, characterization, and catalytic activity. Angewandte Chemie International Edition, 2000. 39(8). p 1499−1501.
- Kloetstra, K. R, H.W. Zandbergen, and H. van Bekkum, Catal. Lett., 1995. 33: p. 157.
- Kloetstra, K.R., H.W. Zandbergen, J.C. Jansen, and H. van Bekkum, Overgrowth of mesoporous MCM-41 on faujasite. Microporous materials, 1996. 6(5−6 Amsterdam, Netherlands): p. 287−293.
- Naydenov, V., L. Tosheva, and J. Sterte, Self-bonded zeolite Beta/MCM-41 composite spheres. Journal of Porous Materials, 2005. 12(3): p. 193−199.
- Kloetstra, K.R., H. Van Bekkum, and J.C. Jansen, Mesoporous material containing framework tectosilicate by pore-wall recrystallization. Chemical Communications, 1997(23): p. 2281−2282.
- Huang, L., W. Guo, P. Deng, Z. Xue, and Q. Li, Investigation of synthesizing MCM-41/ZSM-5 composites. Journal of Physical Chemistry B, 2000. 104(13): p. 2817−2823.
- On, D.T., D. Lutic, and S. Kaliaguine, An example of mesostructured zeolitic material: UL-TS-1. Microporous and Mesoporous Materials, 2001.44−45: p. 435−444.
- Trong On, D. and S. Kaliaguine, Large-pore mesoporous materials with semi-crystalline zeolitic frameworks. Angewandte Chemie International Edition, 2001. 40(17): p. 32 483 251.
- Verhoef, M.J., P.J. Kooyman, J.C. Van d
- Ungureanu, A., D. Trong On, E. Dumitriu, and S. Kaliaguine, Hydroxylation of 1-naphthol by hydrogen peroxide over UL-TS-1 and TS-1 coated mcf. Applied Catalysis A: General, 2003.254(2): p. 203−223.
- Campos, A A., C.R. Silva, M. Wallau, L.D. Dimitrov, and E.A. Urquieta-Gonzalez, Recrystallisation of SBA-15 into ZSM-5/SBA-15 composites. Studies in Surface Science and Catalysis, 2005.158 A: p. 573−580.
- Hoang, V.-T., Q. Huang, A. Malekian, M. Eic, T.-O. Do, and S. Kaliaguine, Diffusion characterization of a novel mesoporous zeolitic material. Adsorption, 2005. 11(1 SUPPL.): p. 421−426.
- Ogura, M., Y. Zhang, S.P. Elangovan, S.P. Naik, and T. Okubo, Preparation of zeolitic mesoporous aluminosilicate by vapor phase transport method. Studies in Surface Science and Catalysis, 2005. 158 A: p. 493−500.
- Huang, Q., H. Vinh-Thang, A. Malekian, M. Eic, D. Trong-On, and S. Kaliaguine, Adsorption of n-heptane, toluene and o-xylene on mesoporous UL-ZSM5 materials. Microporous and Mesoporous Materials, 2006. 87(3): p. 224−234.
- Trong On, D. and S. Kaliaguine, Ultrastable and highly acidic, zeolite-coated mesoporous aluminosilicates. Angewandte Chemie International Edition, 2002.41(6): p. 1036−1040.
- Trong-On, D., A. Ungureanu, and S. Kaliaguine, TS-1 coated mesocellular titano-silica foams as new catalysts for oxidation of bulky molecules. Physical Chemistry Chemical Physics, 2003. 5(16): p. 3534−3538.
- Liu, Y. and T.J. Pinnavaia, Aluminosilicate mesostructures with improved acidity and hydrothermal stability. Journal of Materials Chemistry, 2002. 12(11): p. 3179−3190.
- Liu, Y. and T.J. Pinnavaia, Assembly of hydrothermally stable aluminosilicate foams and large-pore hexagonal mesostructures from zeolite seeds under strongly acidic conditions. Chemistry of Materials, 2002. 14(1): p. 3−5.
- Liu, J., X. Zhang, Y. Han, and F -S. Xiao, Direct observation of nanorange ordered microporosity within mesoporous molecular sieves Chemistry of Materials, 2002 14(6): p 2536−2540.
- Naik, S.P., A.S.T. Chiang, R.W. Thompson, F.C. Huang, and II.-M. Kao, Mesoporous silica with short-range MFI structure. Microporous and Mesoporous Materials, 2003. 60(1−3). p 213−224.
- Prokesova, P., N. Petkov, J. Cejka, S. Mintova, and T. Bein, Micro/mesoporous composites based on colloidal zeolite grown in mesoporous matrix. Collection of Czechoslovak Chemical Communications, 2005. 70(11): p 1829−1847.
- Gies, II., S. Grabowski, and W. Grunert, Micro-mesoporous MCM-48 synthesised with metal-substituted zeolite seeds. Studies in Surface Science and Catalysis, 2004. 154 Π‘: p 2869−2875.
- Xia, Y. and R. Mokaya, On the synthesis and characterization of ZSM-5/MCM-48 aluminosilicate composite materials. Journal of Materials Chemistry, 2004. 14(5): p. 863 870.
- Li, Y., J. Shi, II. Chen, Z. Hua, L Zhang, M. Ruan, J. Yan, and D. Yan, One-step synthesis of hydrothermally stable cubic mesoporous aluminosilicates with a novel particle structure. Microporous and Mesoporous Materials, 2003. 60(1−3): p 51−56.
- Agundez, J., I. Diaz, C. Marquez-Alvarez, E Sastre, and J. Perez Pariente, Ordered assembling of precursors of colloidal faujasite mediated by a cationic surfactant. Studies in Surface Science and Catalysis, 2002. 142 B: p. 1267−1274.
- Liu, Y, W Zhang, and TJ. Pinnavaia, Steam-stable aluminosilicate mesostructures assembled from zeolite type Y seeds 8. Journal of the American Chemical Society, 2000. 122(36). p 8791−8792.
- Liu, Y., W. Zhang, and T.J. Pinnavaia, Steam-stable MSU-S aluminosilicate mesostructures assembled from zeolite ZSM-5 and zeolite Beta seeds Angewandte Chemie International Edition, 2001.40(7): p. 1255−1258.
- Bagshaw, S A., S. Jaenicke, and C.G. Khuan, Structure and properties of Al-MSU-S mesoporous catalysts- Structure modification with increasing al content. Industrial and Engineering Chemistry Research, 2003. 42(17): p. 3989−4000.
- Guo, W, C. Xiong, L. Huang, and Q. Li, Synthesis and characterization of composite molecular sieves comprising zeolite Beta with MCM-41 structures. Journal of Materials Chemistry, 2001. 11(7): p. 1886−1890.
- Wang, Y.J., Y. Tang, Z. Ni, W.M. Ilua, W.L. Yang, X.D. Wang, W. C Tao, and Z Gao, -synthesis of macroporous materials with zeolitic microporous frameworks by self-assembly of colloidal zeolites Chemistry Letters, 2000(5): p 510−511.
- Bagshaw, S A., S Jaenicke, and C.G. Khuan, Eeffect of Al content on the assembly of Al-MSU-S mesostructures: Zeolite seed structure change from zeolite LZY to LTA with increasing Al content. Catalysis Communications, 2003.4(3): p 140−146.
- Borade, R B. and A. Clearfield, Catal. Lett., 1995. 31: p. 267−272.
- Perego, Π‘. and P. Ingallina, Recent advances in the industrial alkylation of aromatics1 New catalysts and new processes Catalysis Today, 2002. 73(1−2): p. 3−22.
- Harmer, M.A. and K.W. Ilutchenson, Super acid catalysis in supercritical fluid reaction media for the formation of linear alkyl benzenes. Chemical Communications, 2002(1): p 18−19.
- Luong, B.X., A.L. Petre, W.F. Hoelderich, A. Commarieu, J.-A. Laffitte, M Espeillac, and J.-C. Souchet, Use of methanesulfonic acid as catalyst for the production of linear alkylbenzenes Journal of Catalysis, 2004. 226(2): p. 301−307.
- Zhao, Z., Z. Li, W. Qiao, G. Wang, and L. Cheng, An efficient method for the alkylation of «-methylnaphthalene with various alkylating agents using methanesulfonic acid as novel catalysts and solvents Catalysis Letters, 2005. 102(3−4): p. 219−222.
- Yadav, G. I), and N S. Doshi, Synthesis of linear phenyldodecanes by the alkylation of benzene with 1-dodecene over non-zeolitic catalysts. Organic Process Research and Development, 2002 6(3): p. 263−272.
- Awate, S.V., S.B. Waghmode, and M S. Agashe, Synthesis, characterization and catalytic evaluation of zirconia-pillared montmorillonite for linear alkylation of benzene Catalysis Communications, 2004. 5(8): p 407−411.
- Asakura, H. and H. Tomioka, Alkylation of diphenyl oxide with long chain olefins using smectite clay catalysts. Nippon Kagaku Kaishi, 2002(1): p 37−46.
- Devassy, B. M, F. Lcfebvre, and S.B. Halligudi, Zirconia-supported 12-tungstophosphoric acid as a solid catalyst for the synthesis of linear alkyl benzenes. Journal of Catalysis, 2005.231(1): p. 1−10.
- Wang, J. and H.-O. Zhu, Alkylation of 1-dodecene with benzene over H3PW12040 supported on mesoporous silica SBA-15. Catalysis Letters, 2004. 93(3−4): p. 209−212.
- Zhang, J., B. Chen, C. Li, Z. Zhu, L. Wen, and E. Min, Kinetics of benzene alkylation with 1-dodecene over a supported tungstophosphoric acid catalyst. Applied Catalysis A. General, 2003. 249(1). p. 27−34.
- RT, S. and H. AM, Alkylation of benzene with dodecene-1 catalyzed by supported silicotungstic acid. Ind Eng Chcm Process Des Develop, 1971. 10(2): p. 272−279.
- RT, S. and II. AM, Alkylation of benzene with dodecene-1 catalyzed by supported silicotungstic acid. Amcr Chem Soc, Div Petrol Chem, 1969. 14(3).
- Sawant, D P. and S Π Halhgudi, Alkylation of benzene with a-olefins over zirconia supported 12-silicotungstie acid. Journal of Molecular Catalysis A: Chemical, 2005. 237(1−2): p. 137−145.
- Bordoloi, A, N.T. Mathew, B.M. Devassy, S.P. Mirajkar, and S.B. Halligudi, Liquid-phase veratrole acylation and toluene alkylation over W0x/Zr02 solid acid catalysts Journal of Molecular Catalysis A: Chemical, 2006. 247(1−2): p. 58−64
- Devassy, Π M, F. I efcbvre, W. Bohringer, J. Fletcher, and S.B. Halligudi, Synthesis of linear alkyl benzenes over zirconia-supported 12-molybdophosphoric acid catalysts. Journal of Molecular Catalysis A: Chemical, 2005 236(1−2): p. 162−167.
- Xin, H., Q Wu, M. Han, D. Wang, and Y. Jin, Alkylation of benzene with 1-dodecene in ionic liquids rmim. +A12C16x- (r = butyl, octyl and dodecyl- x = chlorine, bromine and iodine). Applied Catalysis A: General, 2005. 292(1−2): p. 354−361.
- Qiao, K. and Y. Deng, Alkylations of benzene in room temperature ionic liquids modified with hcl. Journal of Molecular Catalysis A: Chemical, 2001. 171(1−2): p. 81−84.
- DeCastro, Π‘, E. Sauvage, M.H. Valkenberg, and W.F. Ilolderich, Immobilised ionic liquids as lewis acid catalysts for the alkylation of aromatic compounds with dodecene. Journal of Catalysis, 2000.196(1): p. 86−94.
- Zhao, Z -Π, W.-H. Qiao, Z -S Li, G.-R. Wang, and L.-B. Cheng, Friedel-Craftb alkylation of Ρ-methylnaphthalene in the presence of ionic liquids Journal of Molecular Catalysis Π Chemical, 2004. 222(1−2). p. 207−212.
- Zhao, Z, W. Qiao, G. Wang, Z. Li, and L. Cheng, Alkylation of a-methylnaphthalene with long-chain alkenes catalyzed by butylpyridinium bromochloroaluminate ionic liquids Journal of Molecular Catalysis A- Chemical, 2005. 231(1−2): p. 137−143.
- Zhao, Z, W. Qiao, X. Wang, G. Wang, Z. Li, and L. Cheng, Effects of kinds of ionic liquid catalysts on alkylations of 1-and 2-methyInaphthalene with alkenes Applied Catalysis A: General, 2005. 290(1−2): p. 133−137.
- Zhao, Z, B. Yuan, W. Qiao, Z. Li, G. Wang, and L. Cheng, Ihe metal ion modified ionic liquids promoted free-solvent alkylations of a-methylnaphthalene with long-chain olefins Journal of Molecular Catalysis A: Chemical, 2005 235(1−2): p. 74−80.
- Dube, D, S. Royer, D. Irong On, F. Beland, and S. Kaliaguine, Aluminum chloride grafted mesoporous molecular sieves as alkylation catalysts. Microporous and Mesoporous Materials, 2005. 79(1−3): p. 137−144.
- ΠΠΈ, X., M.L. Foo, G.K. Chuah, and S. Jaenicke, Pore size engineering on MCM-41: Selectivity tuning of heterogenized A1C13 for the synthesis of linear alkyl benzenes. Journal of Catalysis, 2000. 195(2) p 412−415.
- Boveri, M., J. Aguilar-Pliego, J. Perez-Pariente, and E Sastre, Optimization of the preparation method of HS03-functionalized MCM-41 solid catalysts. Catalysis Today, 2005. 107−108: p.868−873.
- Goncalves de Almeida, J L, M. Dufaux, Y.B. Taarit, and C. Naccache, Effect of pore si/e and aluminum content on the production of linear alkylbenzenes over HY, H-ZSM-5 and
- H-ZSM-12 zeolites: Alkylation of benzene with 1-dodecene. Applied Catalysis A: General, 1994. 114(1 Amsterdam, Netherlands) — p 141−159.
- Meriaudeau, P., Y. B 1'aarit, A. lhangaraj, J.L.G. Almeida, and C. Naccache, Zeolite based catalysts for linear alkylbenzene production: Dehydrogenation of long chain alkanes and benzene alkylation. Catalysis Today, 1997. 38(2): p 243−247.
- Cao, Y., R. Kessas, C. Naccachc, and Y. Ben Taarit, Alkylation of benzene with dodecene. 1 he activity and selectivity of zeolite type catalysts as a function of the porous structure. Applied Catalysis A- General, 1999. 184(2) — p. 231−238.
- Wang, Π., C.W. Lee, T.-X. Cai, and S.-E. Park, Benzene alkylation with 1-dodecene over Y zeolite. Bulletin of the Korean Chemical Society, 2001. 22(9): p 1056−1058.
- Wang, Π, Π‘ W. Lee, T.-X. Cai, and S.-E. Park, Benzene alkylation with 1-dodecene over h-mordemte zeolite Catalysis Letters, 2001. 76(1−2): p. 99−103.
- Da, Z, Z. Han, P. Magnoux, and M. Guisnet, Liquid-phase alkylation of toluene with long-chain alkenes over HFAU and HBEA zeolites. Applied Catalysis A: General, 2001. 219(1−2): p. 45−52.
- Mayerova, J., J. Pawlcsa, N. Zilkova, G. Kosova, and J. Ccjka, Microporous and mesoporous molecular sieves for alkylation of toluene with olefins. Studies in Surface Science and Catalysis, 2005. 158 B: p. 1945−1952.
- Zhao, Z.-K., Z.-S. Li, W.-H. Qiao, G.-R. Wang, and L.-B. Cheng, Alkylation of u-methylnaphthalene with long-chain olefins over large-pore zeolites. Catalysis Letters, 2004. 98(2−3): p. 145−151.
- I’sai, Π.-Π‘., I. Wang, S.-J. Li, and J.-Y. Liu, Development of a green lab process: Alkylation of benzene with 1-dodecene over mordenite. Green Chemistry, 2003. 5(4): p. 404−409.
- ΠΠ°ΠΏ, M., Z. Cui, C. Xu, W. Chen, and Y. Jin, Synthesis of linear alkylbenzene catalyzed by HP-zeolite. Applied Catalysis A: General, 2002. 238(1) — p 99−107.
- Dwycr, FG, Q.N. Le, and MO. Corporation, Aromatics alkylation process. 1993. US Patent 5,191,135.
- Smith, L A, Jr. and J R Adams, Alkylation of organic aromatic compounds 1990 US Patent 5,019,669.
- Amarilli, S, C. Perego, G. Bellussi, G. Colombo, and S.I. S. p A., Catalytic composition for the preparation of long-chain alkylaromatic compounds. 1996. US Patent 6,204,423.
- Kocal, J.A. and UOP, Detergent alkylation process using a fluorided silica-alumina 1993 US Patent 5,196,574.
- Marinangcli, R.E., R.J. Lawson, L.B. Galperin, T.R. Fritsch, and U. LLC, Arylalkane compositions produced by isomerization, dehydrogenation, and alkylation. 2002
- Thomas, B. and S. Sugunan, Influence of residual cations (Na+, K+ and Mg2+) in the alkylation activity of benzene with 1-octenc over rare earth metal ion exchanged FAU-Y zeolite. Microporous and Mesoporous Materials, 2004. 72(1−3). p. 227−238.
- Zinner, L Π., Π. Zinner, M. Ishige, and A.S. Araujo, Catalytic activity of lanthanide-doped Y zeolite on the alkylation of benzene with 1-dodecene model reaction. Journal of Alloys and Compounds, 1993. 193(1−2): p 65−67.
- I Ian, M., C. Xu, J. Lin, Y. Liang, and E. Roduner, Alkylation of benzene with long-chain olefins catalyzed by fluorinated 3 Zeolite. Catalysis Letters, 2003. 86(1−3): p. 81−86.
- Knifton, J F, F.R. Anantaneni, F E Dai, and M E. Stockton, A new, improved, solid-acid catalyzed process for generating linear alkylbenzenes (LABs) Catalysis Letters, 2001. 75(1−2): p 113−117.
- Knifton, J.F., F.R. Anantaneni, P. E Dai, and ME Stockton, Reactive distillation for sustainable, high 2-phenyl LAB production Catalysis Today, 2003. 79−80: p 77−82
- Anantaneni, P., Rao and II P. Corporation, Process and system for alkylation of aromatic compounds. 2001. US Patent 6,315,964.
- Anantaneni, P. R and H.P. Corporation, Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites. 2000. US Patent 6,166,281.
- Anantaneni, P, Rao and HP. Corporation, Alkylation of benzene to form linear alkylbenzenes using fluorine- containing mordenites. 2000. US Patent 6,133,492.
- Knifton, J.F., P R. Anantaneni, P.E. Dai, and H.F. Corporation, Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites. 1998. US Patent 5,847,254.
- Knifton, J F., P.R. Anantaneni, P.E. Dai, and I LP. Corporation, Iwo-step process for alkylation of benzene to form linear alkylbenzenes. 1998. US Patent 5,777,187.
- Knifton, J.F., P.R. Anantaneni, P.E. Dai, and I LP. Corporation, Process and system for alkylation of aromatic compounds 1998. US Patent 5,770,782.
- ΠΠ²ΡΡ ΡΡΠ°Π΄ΠΈΠΉΠ½ΡΠΉ ΡΠΏΠΎΡΠΎΠ± Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π±Π΅Π½Π·ΠΎΠ»Π° Ρ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ Π»ΠΈΠ½Π΅ΠΈΠ½ΡΡ Π°Π»ΠΊΠΈΠ»Π±Π΅Π½Π·ΠΎΠ»ΠΎΠ². ΠΠ°ΡΠ΅Π½Ρ Π ΠΎΡΡΠΈΠΉΡΠΊΠΎΠΉ Π€Π΅Π΄Π΅ΡΠ°ΡΠΈΠΈ 2 173 677, 2001.
- Tanabe, Π. and W.F. Ilolderich, Industrial application of solid acid-base catalysts. Applied Catalysis A: General, 1999. 181(2): p. 399−434.
- Armor, J.N., New catalytic technology commercialized in the USA during the 1990s Applied Catalysis A: General, 2001.222(1−2): p. 407−426.
- Kocal, J. A, B.V. Vora, and T. Imai, Production of linear alkylbenzenes. Applied Catalysis A- General, 2001. 221(1−2) p. 295−301.
- Galarneau, A, D Desplantier, R Dutartre, and F. Di Renzo, Micelle-templated silicates as a test bed for methods of mesopore size evaluation Microporous and Mesoporous Materials, 1999.27(2−3): p 297−308.
- ΠΠ΅ΡΡΠ΅ΡΠ΅Π½ΠΊΠΎ, H.C. ΠΠΈΡΡΠ΅ΡΡΠ°ΡΠΈΡ Π½Π° ΡΠΎΠΈΡΠΊΠ°Π½ΠΈΠ΅ ΡΡΠ΅Π½ΠΎΠΉ ΡΡΠ΅ΠΏΠ΅Π½ΠΈ ΠΊΠ°Π½Π΄ΠΈΠ΄Π°ΡΠ° Ρ ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΡ Π½Π°ΡΠΊ. 2003.
- ΠΠΎΠ»ΡΠ±Π΅ΡΠ³, Π A and ΠΠ‘. ΠΠΈΠ³Π΄Π΅ΡΠ³Π°ΡΠ·, ΠΡΡΡ Π³Π°Π·ΠΎΠ²ΠΎΠΉ Ρ ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΠΈ. ΠΠ·Π΄Π°ΡΠ΅Π»ΡΡΡΠ²ΠΎ «Π₯ΠΈΠΌΠΈΡ», ΠΠΎΡΠΊΠ²Π°, 1967
- ΠΠ΅ΡΠ΅Π², II. and Π. ΠΠΎΡΠ΅Π², Π‘ΠΏΡΠ°Π²ΠΎΡΠ½ΠΈΠΊ ΠΏΠΎ ΠΌΠ·ΠΎΠ²ΠΎΠΉ Ρ ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΠΈ. ΠΠ·Π΄Π°ΡΠ΅Π»ΡΠΌΠ²ΠΎ «ΠΠΈΡ», ΠΠΎΡΠΊΠ²Π°, 1987.
- Ogura, Π, J. Tateno, and Y. Nara, Alkali-treatment new method for modification of structural and acid — catalytic properties of ZSM-5 zeolites. Applied Catalysis A: General, 2001. 219(1−2): p. 33−43.
- Broekhoff, J. and e. al., Studies on pore systems in catalysis. Journal of Catalysis, 1967. 9 p. 15−27.
- Marie, Π., P Massiani, F. Thibault-Starzyk, and et. al., Infrared evidence of a third bronsted site in mordemtes Microporous and Mesoporous Materials, 2004.
- Datka, J., B. Gil, and J. Weglarski, Heterogeneity of oh groups in mordenites- ir studies of benzene and carbon monoxide sorption and nmr studies. Microporous and Mesoporous Materials, 1998.21: p. 75−79.
- Bordiga, S. and etal., Fourier-transform infrared study of ΡΠΎ adsorbed at 77 ΠΊ on H-mordenite and alkali-metal-exchanged mordenites. Langmuir, 1995. 11: p. 527−533.
- Isyganenko, A A, KM. Bulanin, P.Y. Storozhev, S. Ilaukka, A Palukka, and M Lindblad, Study of layer-by-layer growth of silica on alumina and alumina on silica using spectroscopy of adsorbed ΡΠΎ. Stud Surf. Sci. Catal, 2000. 130. p. 3149−3154.