Синтез, комплексообразование и фотохромные свойства краунсодержащих спиронафтоксазинов
Kimura K., Yamashita Т., Yokoyama M. Syntheses, Cation Complexation, Isomerization and Photochemical Cation-Binding Control of Spirobenzopyrans Carrying a Monoazacrown Moiety at the 8-Position. // J. Chem. Soc., Perkin Trans. 2. 1992. — P. 613−619. Swansburg S., Choi Y. K., Keum S. R., Buncel E., Lemieux R. P. Synthesis and Characterization of Liquid Crystals Containing a Non-Activated 1 ', 3… Читать ещё >
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1. Разработаны методы синтеза б'-аминосодержащих спиронафтоксазинов включая б'-азакраунсодержащие спиронафтоксазины. Впервые выделено промежуточное соединение в синтезе спиронафтоксазинов из 1-амино-2-нафтола и основания Фишера, позволяющее предложить схему механизма реакции конденсации.
2. Разработаны методы синтеза спиронафтоксазинов на основе бензотиазола и дигидроизохинолина, содержащих краун-эфирный фрагмент в гетероциклической части молекулы и устойчивых преимущественно в закрытой или открытой формах.
3. С использованием электронной, ЯМР-спектроскопии и флэш-фотолиза изучено комплексообразование краунсодержащих спиронафтоксазинов. Установлено, что они являются дитопными рецепторами, причем два места связывания отличаются по селективности и влиянию процесса комплексообразования с катионами металлов на оптический отклик.
4. Установлено, что комплексообразование эффективно влияет на спектральные и фотохромные характеристики краунсодержащих спиронафтоксазинов. На примере б'-азакраунсодержащих спиронафтоксазинов показана возможность фотоуправления их комплексообразующей способностью.
5. Обнаружена и изучена реакция образования производных оксазола из мероцианиновой формы б'-аминосодержащих спиронафтоксазинов в присутствии катионов свинца и редкоземельных металлов.
Синтез, комплексообразование и фотохромные свойства краунсодержащих спиронафтоксазинов (реферат, курсовая, диплом, контрольная)
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